Ma'bad al-Juhani narrates from Sayyiduna Mu'awiyah (may Allah be pleased with him) that he said: "You pray this prayer, yet we kept the company of the Messenger of Allah (peace and blessings be upon him) and saw him, and we never saw him (peace and blessings be upon him) pray this prayer after the prayer," meaning after Asr.
Hadith Referenceالمعجم الكبير للطبراني / باب الميم / 16867